Phosphazene Chemistry Research Laboratory

Laboratory Name  Phosphazene Chemistry Research Laboratory
Laboratory Responsible Prof.Dr. Adem KILIÇ
Department Chemistry 
Telephone +90 (262) 6053111-3119
Address Gebze Institute of Technology, Faculty of Science, Chemistry Department, Muallimköy Campus, P.O.Box 141 Gebze-Kocaeli, 41400, TURKEY
General Information Goals and purpose
Our research group is focused its attention to the synthesis and characterization of new phosphazene compounds which may have possible industrial applications (such as LED,PEM FC, Solar Cells etc.) and biological properties. 
Research interest:
- Synthesis of alternative anhydrous proton conducting polymer membranes based on acid substituted polyaryloxyphosphazenes, acid substituted pendant aryloxycyclophosphazene bearing hybrid polymers and acid bearing pendant aryloxycyclophosphazene-vinyltriazole hybrid co-polymers.
- Synthesis of some rotaxanes which are an important class of nanomachines and investigation of their electrochemical properties. 
- Synthesis of new types of full substitute spermine bridged cyclophosphazene compounds which are thought to be potentially biologically active molecules
- Synthesis of new types of fluorenylidene bridged cyclophosphazene compounds which are thought to be potentially biologically active molecules and investigations of anti-tumor properties for tumor cells in vitro.
- Synthesis and investigation of properties of conjugated dendrimeric pyrene derivatives based on cyclic phosphazene core for organic light emitting diodes.
- Synthesis and investigation of fluorescence phosphazene compounds.
- Investigation of the reactions of cyclotriphosphazenes bearing Ph, Sph, OPh, NHPh functional groups with 4-isopropylaniline and investigation of photophisycal properties of new compounds. 
- Investigation of the reactions of cyclotriphosphazatriene derivatives having long alkyl chain with various transition metals. 
Laboratory Staff Prof. Dr. Adem Kılıç
Prof. Dr. Serap Beşli
Asoc. Prof. Dr. Aylin Uslu 
Asoc. Prof. Dr. Serkan Yeşilot
Asoc. Prof. Dr. Hanife İbişoğlu
Asoc. Prof. Dr. Gönül Yenilmez Çiftçi
Asist. Prof. Dr. Ferda Hacıvelioğlu
Res. Assist. Dr. Şule Şahin Ün
Res. Assist. Dr. Esra Tanrıverdi Eçik 
Spec. Dr. Bünyemin Çoşut
PhD students: Res. Assist. Elif Okutan, Res. Assist. Seda Çetindere, Res. Assist. Hüsniye Ardıç, Spec. İlker Ün, Elif Şenkuytu, Özlem Gırgıç,
MSc students: Ömer Faruk Çiftbudak, Elif Özcan, Şükriye Yılmaz, Elif Büşra Çelebi, Elif İncir
Applications *Synthesis and characterization of cyclophosphazene and polyphosphazene derivatives
* photophysical and photochemical measurements
* Liquid crystal studies
Equipment Equipments for synthesis:
-Heidolph Hei-VAAP advantage Evaporator
Equipments for characterization:
-NMR, FT-IR, UV-Vis, MS (MALDİ,ES VE APCI), Single crystal X-ray diffractometer
Projects “Synthesis of Boradiazaindacene Substituted Cyclophosphazene Compounds and Investigation of Their Properties” BAP (BAP 2011-A-12) (2011-2013) Coordinator: Prof. Dr. Adem KILIÇ

“Synthesis of Cyclotriphosphazene Compounds with Transition Metals” GYTE-BAP (2011-2012) Coordinator: Prof. Dr.Serap BEŞLİ

“The Synthesis and Characterization of Some Rotaxane Complexes” TÜBİTAK (TBAG-111T042) (2012-2013) Coordinator: Assoc.Prof.Dr.Aylin USLU
“Synthesis and Characterizations of Novel Aminocyclotriphosphazenes
” BAP (BAP 2011 - A – 17) (2011-2012)Coordinator: Assoc.Prof.Dr. Hanife İBİŞOĞLU

“The Synthesis of New Type Full Substituted Spermine Bridged Cyclophosphazene which is Potential Biologically Active Molecules ”BAP(2011-A-04) (2011-2012) Coordinator: Assoc.Prof. Dr.Gönül YENİLMEZ ÇİFTÇİ
“The Synthesis of Fluorenylidene- Bridged Cyclophosphazenes, Characterization and The Investigation of Fluorescence and Biological Activity” TÜBİTAK (TBAG-111T085) (2011-2013) Coordinator: Assoc.Prof. Dr.Gönül YENİLMEZ ÇİFTÇİ
“Synthesis of dendrimeric pyrene derivatives based on cyclic phosphazenes and investigation of their thermal stability, photopysical and electroluminescence properties” TUBİTAK, (2010-2013) Coordinator: Assoc.Prof. Dr.Serkan YEŞİLOT
“Investigation of Reactions of Some Phosphazene Derivatives with 4-isopropylaniline” GYTE BAP-2011-A16 (2011-2012) Coordinator: Assoc.Prof.Dr.Aylin USLU
“Synthesis, Characterization and Fuel Cell Applications of Phosphazane Based Anhydrous Polymer Electrolyte Membranes ”
TÜBİTAK (2010-2012) Coordinator : Asist.Prof.Dr. Ferda HACIVELİOĞLU

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