Dr. İdris KARAKAYA
Chemistry

İdris KARAKAYA
Phone
+90 (262) (262) 605 30 57
Email
karakayagtu.edu.tr
Office
, 205
Areas of interest
Synthesis of organic compounds (basicly asymmetric synthesis) Transfer Hydrogenation Reactions Synthesis of potential biologically active heterocyclic compounds Photoredox Cross-Coupling

Journal Article

A17. Rizwan, K. Karakaya, I. Zubair, M. and Rasool, N., Palladium catalyzed cross-coupling of 3-methylthiophene-2-carbonyl chloride with aryl/het-aryl boronic acids: a convenient method for synthesis of thienyl ketones, JOURNAL OF SULFUR CHEMISTRY, 2022, doi.org/10.1080/17415993.2022.2079379
A16. Karakaya I. Facile Synthesis of Fully Conjugated Aminopyrazine Based Diazobenzenes and Diazoaminobenzenes with Aryldiazonium Salts, HETEROCYCLES, Vol 104, No. 7, 2022, DOI: 10.3987/COM-22-14664
A15. Karakaya I. Synthesis and Characterization of Azobenzene Derived from 8-aminoquinoline in Aqueous Media. JOTCSA. 2022;9(1):85–92.doi.org/ 10.18596/jotcsa.1012453
A14. Karakaya, I. Amphiphilic Polypyridyl Ruthenium Catalyzed, Photoredox- Mediated C-H Arylation of Heteroarenes with Aryl Diazonium Salts. ChemistrySelect, 2021, 6, 11551–11556 doi.org/10.1002/slct.202103566.
A13. Karimi-Nami, R.; Adib, M.; Heydari, F.; Rajai-Daryasarei, S.; Karakaya, I.; Phosphorylation of 2-Aryl Quinoxaline Derivatives via C-H/P-H Cross Coupling under Transition-Metal-Free Conditions. Polycyclic Aromatic Compounds, 2021, doi.org/10.1080/10406638.2021.1983619, Article in Press
A12. Ejaz, S.; Zubair, M.; Rizwan, K.; Karakaya, I.; Rasheed, T.; Rasool N.; An updated coverage on synthesis of benzo[b]thiophenes via transition metal catalyzed reactions: A review. Current Organic Chemistry 2021; 25(1). https://doi.org/10.2174/1385272824999201111204317
A11. Agac, A.; Karakaya, I.; Sahin, I.; Emir, S.; Karabuga, S.; Ulukanli, S.; Synthesis of aminomethyl quinazoline based ruthenium (II) complex and its application in asymmetric transfer hydrogenation under mildconditions. Journal of Organometallic Chemistry 819 (2016) 189-193.
A10. Sahin, I.; Emir, S.; Ispir, E.; Karakaya, I.; Gumus, S.; Ulusoy, M.; Karabuga. S.; Hydroxyl group effect in novel NNN type pyridine based ruthenium (II) complex for the transfer hydrogenation of ketones Catalysis Communications 2016, 85, 30-33.
A9. Karakaya, I.; Karabuga, S.; Mart, M.; Altundas, R.; Ulukanli, S.; Synthesis and Catalytic Asymmetric Applications of Quinazolinol Ligands. Synthesis 2016 48, Doi: 10.1055/s-0035-1561584.
A8. Kucukturkmen, C.; Agac, A.; Eren, A.; Karakaya, I.; Aslantas, M.; Celik, O.; Ulukanli, S.; Karabuga, S.; Asymmetric transfer hydrogenation of ketones by N,N-containing quinazoline-based ruthenium(II) complexes. Catalysis Communications 2016, 74, 122-125.
A7. Rizwan, K.; Karakaya, I.; Heitz D.; Zubair M.; Rasool N.; Molander G. A.; Copper-mediated N-arylation of methyl 2-aminothiophene-3-carboxylate with organoboron reagents. Tetrahedron Lett., 2015, 56, 6839–6842.
A6. Karakaya, I.; Primer, D. N.; Molander, G. A.; Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers. Org. Lett. 2015, 17, 3294−3297
A5. Primer, D. N.; Karakaya, I.; Tellis, J. C.; Molander, G. A.; Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling. J. Am. Chem. Soc. 2015, 137 (6), pp 2195–2198.
A4. Karabuga S.; Bars, S.; Karakaya, I.; Gumus, S. Efficient transfer hydrogenation reactions with quinazoline-based ruthenium complexes. Tetrahedron Lett. 2015, 56, 101–104.
A3. Karabuga, S.; Karakaya, I.; Ulukanli, S.; 3-Aminoquinazolinones as chiral ligands in catalytic enantioselective diethylzinc and phenylacetylene addition to aldehydes. Tetrahedron Asymmetry 2014, 25, 851–855.
A2. Karakaya, I.; Karabuga, S.; Altundas, R.; Ulukanli, S.; Synthesis of quinazoline based chiral ligands and application in the enantioselective addition of phenylacetylene to aldehydes. Tetrahedron 2014, 70, 8385–8388.
A1. Karakaya, I.; Karabuga, S.; Ulukanli, Z.; Ulukanli, S.; Synthesis and antifungal evaluation of imines derived from 3-Amino-2-isopropyl-3H-quinazolin-4-one.Org. Commun. 6:4 (2013) 139-147.

Conference Proceedings
B9.
Photoredox / Ni Dual Catalysis for the Synthesis of Benzylic Ethers. Anatolian Conference on Synthetic Organic Chemistry ACSOC II 2016, Aydin, Turkey (Oral Presentation)

B8. Asymmetric transfer hydrogenation of ketones by aminomethyl quinazoline based ruthenium (II) complex under mild conditions. Anatolian Conference on Synthetic Organic Chemistry ACSOC II 2016, Aydin, Turkey (Poster)

B7. Hydroxyl group effect in novel NNN type pyridine based ruthenium (II) complex for the transfer hydrogenation of ketones. Anatolian Conference on Synthetic Organic Chemistry ACSOC II 2016, Aydin, Turkey (Poster)

B6. Quinazolinebased ruthenium(II) complexes for asymmetric transfer hydrogenation of ketones. Anatolian Conference on Synthetic Organic Chemistry ACSOC II 2016 (Poster)

B5. Synthesis of heterogeneous ruthenium (II) complex and its application in transfer
hydrogenation reaction. Anatolian Conference on Synthetic Organic Chemistry ACSOC II 2016, Aydin, Turkey (Poster)
B4. Synthesis of Quinazolinone and Quinazoline Based Chiral Alcohols and Application In Catalytic Asymmetric Weitz-Scheffer Epoxidation of Chalcones, Trans Mediterranean Colloquium on Heterocyclic Chemistry TRAMECH VIII, 11-15 November 2015, Antalya, Turkey (Poster)

B3. Synthesis and Asymmetric Catalytic Activity of 4-Phenylquinazolines (XVth Conference on Heterocycles in Bio-organic Chemistry May 27-30, 2013, Riga, Latvia) (Poster)

B2. Synthesis of Quinazolinols as chiral catalysts in enantioselective phenylboronic acid addition to aldehydes (Pharmaceutical Chemistry, Production, Technology and Standardization Congress, 29-31 March 2013 Antalya, Turkey) (Poster)

B1. Synthesis and asymmetric catalytic activity of 4-aminoquinazolinone imines in diethylzinc addition to aldehydes (25. National Chemistry Congress 27 june - 2 july 2011 Erzurum Turkey) (Poster)

  • Third Cycle (Doctoral): Atatürk Üniversitesi Fen Bilimleri Enstitüsü,2008-2014
  • Second Cycle (Master's):
  • First Cycle (Undergraduate): Atatürk Üniveristesi, Kazım Karabekir Eğitim Fakültesi, 2002-2007
Post-Doc Researcher: University of University of Pennsylvania, USA, Sept. 2014 – Sept. 2015 (Supervisor: Prof. Dr. Gary A. MOLANDER)
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